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Research Group Domasevitch

Crystal Engineering of Coordination Polymers

Head of the Research group

Doctor of Chemical Sciences, Leading Researcher,

Laureate of the State Prize of Ukraine in the field of science and technology

DOMASEVITCH, KONSTANTIN V.

Office: 401-б (5-th floor)

Phone: +38 (044) 239-33-06

E-mail: This e-mail address is being protected from spambots. You need JavaScript enabled to view it This e-mail address is being protected from spambots. You need JavaScript enabled to view it


Research in the group covers aspects of crystalline engineering, supramolecular, coordination and organic chemistry to understand the basic principles underlying the organization of the crystalline structure of compounds and determine their functional properties (sensing, catalytic, magnetic, etc.).

 

Research group staff members:

ANDREY B. LYSENKO
Position: Senior Researcher
Degree: Candidate (PhD) of Chemical Sciences
Office: 401-b  (5-th floor)
Phone: +38 (044) 239-33-06
E-mail: This e-mail address is being protected from spambots. You need JavaScript enabled to view it

VIRA V. PONOMAROVA
Position: Associate Professor
Degree: Candidate (PhD) of Chemical Sciences
Offices: 400, 401-б (5-th floor)
Phone: +38 (044) 239-33-06
E-mail: This e-mail address is being protected from spambots. You need JavaScript enabled to view it

GANNA A. SENCHYK
Position: Junior Researcher
Degree: Candidate (PhD) of Chemical Sciences
Office: 401-b  (5-th floor)
Phone: +38 (044) 239-33-06
E-mail: This e-mail address is being protected from spambots. You need JavaScript enabled to view it

 

Current research interests:

 

  • Derivatives of pyrazoles for the production of noncentrosymmetric materials.
  • Nitro Derivatives pyrazoles for the production of explosives and propellants.
  • Coordination chemistry of ligands based on adamantane platform.
  • Coordination polymers on the basis of polyoxometallates as promising magnetic and luminescent materials.
  • Molybdenum-organic oxide compounds for catalytic epoxidation of olefins.
  • Coordination polymers of uranium (VI) on the basis of triazolyl and carboxylate bridges.

Selected Publications:

[1]. A. B. Lysenko, G. A. Senchyk, K. V. Domasevitch, M. Kobalz, H. Krautscheid, J. Cichos, M. Karbowiak, P. Neves, A. A. Valente, I. S. Gonçalves. Triazolyl, Imidazolyl, and Carboxylic Acid Moieties in the Design of Molybdenum Trioxide Hybrids: Photophysical and Catalytic Behavior. Inorg. Chem., 2017, 56, 4380–4394.

[2]. T. Zhao, C. Heering, I. Boldog, K. V. Domasevitch, C. Janiak. A view on systematic truncation of tetrahedral ligands for coordination polymers. CrystEngComm201719, 776–780.

[3]. A. B. Lysenko, G. A. Senchyk, L. V. Lukashuk, K. V. Domasevitch, M. Handke, J. Lincke, H. Krautscheid, E. B. Rusanov, K. W. Krämer, S. Decurtins, S.-X. Liu. Composition Space Analysis in the Development of Copper Molybdate Hybrids Decorated by a Bifunctional Pyrazolyl/1,2,4-Triazole Ligand.Inorg. Chem., 2016, 55, 239–250.

[4]. A. Tabacaru, N. Xhaferaj, L. M. D. R. S. Martins, E. C. B. A. Alegria, R. S. Chay, C. Giacobbe, K. V. Domasevitch, A. J. L. Pombeiro, S. Galli, C. Pettinari. Metal azolate/carboxylate frameworks as catalysts in oxidative and C-C coupling reactions. Inorg. Chem., 201655, 5804–5817.

[5]. G. A. Senchyk, E. M. Wylie, S. Prizio, J. E. S. Szymanowski, G. E. Sigmon, P. C. Burns. Hybrid uranyl–vanadium nano-wheels. Chem. Commun.201551, 10134–10137.

[6]. A. B. Lysenko, G. A. Senchyk, K. V. Domasevitch, J. Hauser, D. Fuhrmann, M. Kobalz, H. Krautscheid, P. Neves, A. A. Valente, I. S. Gonçalves. Synthesis and Structural Elucidation of Triazolylmolybdenum(VI) Oxide Hybrids and Their Behavior as Oxidation Catalysts. Inorg. Chem., 2015, 54, 8327−8338.

[7]. G. A. Senchyk, A. B. Lysenko, A. A. Babaryk, E. B. Rusanov, H. Krautscheid, P. Neves, A. A. Valente, I. S. Gonçalves, K. W. Krämer, S.-X. Liu, S. Decurtins, K. V. Domasevitch. Triazolyl−Based Copper−Molybdate Hybrids: From Composition Space Diagram to Magnetism and Catalytic Performance.Inorg. Chem., 2014, 53, 10112−10121.

[8]. S. I. Vasylevs’kyy, G. A. Senchyk, A. B. Lysenko, E. B. Rusanov, A. N. Chernega, J. Jezierska, H. Krautscheid, K. V. Domasevitch, A. Ozarowski. 1,2,4-Triazolyl-Carboxylate-Based MOFs Incorporating Triangular Cu(II)-Hydroxo Clusters: Topological Metamorphosis and Magnetism. Inorg. Chem., 2014,53, 3642−3654.

[9]. A. S. Degtyarenko, M. Handke, K. W. Krämer, S.-X. Liu, S. Decurtins, E. B. Rusanov, L. K. Thompson, H. Krautscheid, K. V. Domasevitch. Mixed-ligand hydroxocopper(II)/pyridazine clusters embedded into 3D framework lattices. Dalton Trans. 2014, 43, 8530–8542.