Coordination compounds based on CAPh and SAPh ligands
Head of the Research group
Doctor of Chemical Sciences, Professor
Offices: 510-б, 508, 508-а (5-th floor)
Tel.: +38 (044) 239-33-92
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Current research interests:
Synthesis and investigation of coordination behaviour of a new powerful ligand systems: carbacylamidophosphates (CAPh) – organic compounds having functional chelate fragment -C(O)N(H)P(O)= and sulfonylamidophosphates (SAPh) – compounds, containing the -S(O)2N(H)P(O)= chelate fragment; their bioactivity. Design of new, based on Ln(III), luminescent coordination compounds for MOLED (metal organic light emmiting diods) devices. CAPh and SAPh – containing transition metal coordination compounds, incuding heterobinuclear 3d-4f complexes and their potential applications based on interesting magnetic, catalytic, luminescence etc. properties.
Research group staff members:
VLADIMIR A. OVCHYNNIKOV
Position: Senior Researcher
Academic rank: Senior Researcher
Degree: Candidate (PhD) of Chemical Sciences
Office: 508, 508-a (5-th floor)
Phone: +38 (044) 239-33-92
E-mail:
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VICTOR A. TRUSH
Position: Senior Researcher
Degree: Candidate (PhD) of Chemical Sciences
Offices: 508, 508-a (5-th floor)
Phone: +38 (044) 239-33-92
E-mail:
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TATIANA Yu. SLIVA
Position: Head of the Laboratory
Academic rank: Senior Researcher
Degree: Candidate (PhD) of Chemical Sciences
Office: 510-b (5-th floor)
Phone: +38 (044) 239-33-92
E-mail:
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KATERYNA E. GUBINA
Position: Associate Professor
Degree: Candidate (PhD) of Chemical Sciences
Office: 507 (5-th floor)
Phone: +38 (044) 239-33-92
E-mail:
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KATERYNA O. ZNOVJYAK
Position: Senior Researcher
Degree: Candidate (PhD) of Chemical Sciences
Office: 401-a (5-th floor)
Phone: +38 (044) 239-33-92
E-mail:
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OLENA O. LITSIS
Position: Junior Researcher
Degree: Candidate (PhD) of Chemical Sciences
Office: 401-a (5-th floor)
Phone: +38 (044) 239-33-92
E-mail:
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NATALIIA S. KARIAKA
Position: Junior Researcher
Degree: Candidate (PhD) of Chemical Sciences
Office: 401-a (5-th floor)
Phone: +38 (044) 239-33-92
E-mail:
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OLESIA V. MOROZ
Position: Junior Researcher
Degree: Candidate (PhD) of Chemical Sciences
Office: 401-a (5-th floor)
Phone: +38 (044) 239-33-92
E-mail:
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SHATRAVA, IULIIA O.
Position: Engineer, 1st cathegory
Offices: 230 (2-nd floor), 508 (5th floor)
Phone: +38 (044) 239-33-92
E-mail:
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Selected Publications:
[1]. Gawryszewska P., Amirkhanov V.M., Trush V.A., Kulesza D., Legendziewicz J. The ligand-to-metal energy transfer and the role of Lewis base ligands and silver plasmons in emission of new type of lanthanide phosphors. Journal of Luminescence. – 2016. – V. 170. – P. 340-347.
[2]. Kasprzycka E., Trush V. A., Jerzykiewicz L., Amirkhanov V.M., Gawryszewska P. Structural and spectroscopic properties of Nd complexes with sulfonylamidophosphate type ligands. Journal of Luminescence – 2016. – V. 170. – P. 348-356.
[3]. Kariaka N.S., Rusanova J.A., Smola S.S., Kolotilov S.V., Znovjyak K.O., Weselski M., Sliva T.Yu., Amirkhanov V.M. First examples of carbacylamidophosphate pentanuclear hydroxocomplexes: Synthesis, structure, luminescence and magnetic properties. Polyhedron. – 2016. - Vol. 106. –P. 44-50
[4]. Litsis O.O., Shatrava Iu.O., Amirkhanov O.V., Оvchynnikov V.A., Sliva T.Yu., Shishkina S.V., Dyakonenko V.V., Shishkin O.V., Аmirkhanov V.M. New carbacylamidophosphates (CAPh) and CAPh containing coordination compounds: structural peculiarities. Structural Chemistry. – 2016. - 27, No 1. – P. 341-355.
[5]. Kariaka N.S., Trush V.A., Medviediev V.V., Dyakonenko V.V., Shishkin O.V., Smola S.S., Fadeyev E.M., Rusakova, N.V., Amirkhanov V.M. Coordination compounds based on CAPh type ligand: Synthesis, structural characteristics and luminescence properties of tetrakis-complexes CsLnL4 with dimethylbenzoylamidophosphate. Journal of Coordination Chemistry. – 2016. – 69, No 1. - P. 123-134.
[6]. Sobczyk M., Korzeniowski K., Guzik M., Amirkhanov V. M., Trush V.A., Gawryszewska P., Guyot Y., Boulon G., Stręk W., Legendziewicz J. Spectral characteristic and crystal- field calculations for new Er(III) phosphor of the type [Er(SP)4]− (where SP=C6H5S(O)2NP(O)(OCH3)2−). Journal of Luminescence. – 2016. – V. 169. – P. 777-781.
[7]. Kariaka N.S., Trush V.A., Gawryszewska P., Dyakonenko V.V., Shishkina S.V., Sliva T.Yu., Amirkhanov V.M. Spectroscopy and structure of [LnL3bipy] and [LnL3phen] complexes with CAPh type ligand dimethylbenzoylamidophosphate. Journal of Luminescence. – 2016. – V. 178. – P. 392-399.
[8]. Znovjyak K. O., Seredyuk M., Kusz J., Nowak M., Moroz O. V., Sliva T. Yu., Amirkhanov V. M. Synthesis, crystal structures and spectroscopic properties of cobalt(II) complexes with chelating sulfonylamidophosphate ligands. Journal of Molecular Structure. – 2015. – 1100. - P.145-149.
[9]. Litsis O.O., Ovchynnikov V.A., Scherbatskii V.P., Nedilko S.G., Sliva T.Yu., Dyakonenko V.V., Shishkin O.V., Davydov V. I., Gawryszewska P., Amirkhanov V.M. Lanthanide Mixed-Ligand Complexes of the [Ln(CAPh)3(Phen)] and [LaxEu1-x(CAPh)3(Phen)] (CAPh= carbacyl-amidophosphate) type. Comparative Study of Their Spectral Properties. Dalton Transactions. – 2015. - V.44. - P.15508-15522.
[10]. Amirkhanov V.M., Ovchynnikov V.A., Trush, V.A., Gawryszewska P., Jerzykiewicz L.B. Powerful new ligand systems: carbacylamidophosphates (CAPh) and sulfonylamidophosphates (SAPh). p. 199 – 248. (Chapter 7. in the book “Ligands. Synthesis, Characterization and Role in Biotechnology. NOVA Publishers, New York, 2014).
[11]. Kariaka N.S., Trush V.A., Sliva T.Yu., Dyakonenko V.V., Shishkin O.V., Amirkhanov V.M. Synthesis and spectral studies of lanthanides coordination compounds based on N-(diphenylphosphoryl)benzamide. The structure of N-(diphenylphosphoryl)benzamide. Journal of Molecular Structure. - 2014. - v. 1068. – p. 71-76.
[12]. Kasprzycka E., Trush V.A., Amirkhanov V.M., Jerzykiewicz L., Gawryszewska P. Structural and photophysical properties of lanthanide complexes with N-(diphenylphosphoryl)-4-methylbenzenesulfonamide. Optical Materials (2014), pp. 476-482.
[13]. Amirkhanov O.V., Moroz O.V., Znovjyak K.O., Sliva T.Yu., Penkova L.V., Yushchenko T., Szyrwiel L., Konovalova I.S., Dyakonenko V.V., Shishkin O.V., Amirkhanov V.M. Heterobinuclear Zn-Ln and Ni-Ln complexes with Schiff-base and carbacylamidophosphate ligands: Synthesis, crystal structures and catalytic activity. European Journal of Inorganic Chemistry. – 2014. - (23), pp. 3720-3730
[14]. Yizhak R.V., Znovjyak K.O., Ovchynnikov V.A., Sliva T.Yu., Konovalova I.S., Shishkin O.V., Amirkhanov V.M. Synthesis and crystal structures of new dioxouranium(VI) complexes based on carbacylamidophosphates (CAPh). Investigation of extraction properties of some CAPh ligands in respect of dioxouranium(VI) nitrate. Polyhedron. – 2013. - Vol. 62. –P. 293-299.
