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Laboratory of Molten Salts Chemistry

Head of the Research group

Head of Inorganic Chemistry Department,

Corresponding Member of the NAS of Ukraine,

Academician of Academy of Sciences of Higher School of Ukraine,

Doctor of Chemical Sciences, Professor

SLOBODYANIK, MYKOLA S.

Offices: 239 (2-nd floor), 315 (3-rd floor);

Phone: +38 (044) 239-32-41; +38 (044) 239-31-38

E-mail: This e-mail address is being protected from spambots. You need JavaScript enabled to view it

AWARDS:

  • Honored Worker of Science and Technology - 2006
  • Corresponding Member of the National Academy of Sciences of Ukraine - 1997
  • Academician of the Academy of Higher Education - 1998
  • Premium of National Academy of Sciences of Ukraine named after L.V. Pisarzhevsky - 1988.

 

The research topics of the research group cover a wide range from fundamental topics like oxides interaction within the molten salts media and crystallization peculiarities of functional oxide materials. The main focus is devoted to correlation between composition and structure of different complex oxide materials with physico-chemical properties including non-linear optic response, luminescence intensity, bioactivity, catalytic performance. He published more than 450 original papers and review articles, 10 patents and 21 school books. He has been a superviser of postgraduate research for Chemistry theses for 4 Doctors of Sciences and 18 Candidates of Sciences (Ph D).

 

Research group staff members:

YURI A. TITOV
Position: Leading Researcher
Academic rank: Senior Researcher
Degree: Doctor of Chemical Sciences
Office: 112-a (1-st floor)
Phone: +38 (044) 239-32-01
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KATERYNA V. TEREBILENKO
Position: Associate Professor
Degree: Candidate (PhD) of Chemical Sciences
Office: 213-б (2-nd floor)
Phone: +38 (044) 239-32-88
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NATALIYA Yu. STRUTYNSKA
Position: Senior Researcher
Degree: Candidate (PhD) of Chemical Sciences
Offices: 31, 208  (2-nd floor)
Phone: +38 (044) 239-32-88
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ROMAN N. KUZ'MIN
Position: Leading Engineer
Office: 23
Phone:
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MARIANA V. TYMOSHENKO
Position: Leading Engineer
Office: 112-b (1-st floor)
Phone: +38 (044) 239-32-01
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Current research interests:

  1. Synthesis and functionalization of oxide materials with non-linear optic response, high luminescence intensity (in close collaboration with physicians), bioactivity and high catalytic performance.
  2. Development and application of solid state matter: single crystals, ceramics, nanopowders and composites;
  3. Crystallization peculiarities of complex oxides,
  4. Crystal structure and reactivity of solids.

Selected Publications:

[1]. Babaryk A.A., Odynets I.V., Khainakov S., Garcia-Granda S., Slobodyanik N.S.  Polyanionic identity of Ca2Zn2(V3O10)(VO4) photocatalyst manifested by X-ray powder diffraction and periodic boundary density functional theory calculations. CrystEngComm. V.17, Is. 40, 2015, P. 7772-7777.

[2]. Strutynska N., Zatovsky I., Malyshenko A., Slobodyanik N.S.,  Prylutskyy Y., Prymak O.,Vorona I., Ishchenko S., Baran, N. Byeda A., Mischanchuk A. Preparation, Characterization, and Thermal Transformation of Poorly Crystalline Sodium- and Carbonate-Substituted Calcium Phosphate. Eur. J. Inorg. Chem. 2015,  P. 622–629.

[3]. Bychkov K.L., Terebilenkо K.V. , Linnik R. P. Effect of Isovalent Substitution on the Formation and Luminescence Properties of Solid Solutions BiPXV1-XO4 Doped with Europium (III) Solid State Phenomena, Vol. 230 – 2015 – pp. 188-192.

[4]. Terebilenko K. V., Bychkov K L., Baumer V.N., Slobodyanik N. S., Pavliuk M. V., Thapper A., Tokmenko I. I., Nasieka I. M., Strelchuk V. V. Structural transformation of Bi1−x/3V1−xMoxO4 solid solutions for light-driven water oxidation,         Dalton Trans., 2016, N9, 45, 3895-3904.

[5]. Zatovsky, I.V., Strutynska N.Y., Ogorodnyk, I.V., Baumer, V.N., Slobodyanik, N.S. Yatskin, M.M., Odynets, I.V.Peculiarity of formation of the NASICON-related phosphates in the space group R32: Synthesis and crystal structures of Na4MIIAl(PO4)3 (MII-Mg, Mn). Structural Chemistry, 2016, Vol. 27, Is. 1, P. 323-330.

[6]. Titov Yu.A., Slobodyanik N. S., Polubinskii V. V., Chumak V. V. Mechanisms for the formation of layered A4B3O12 compounds from coprecipitated hydroxocarbonate and hydroxide systems // Theoretical and Experimental Chemistry, 2011, V. 48, N 6, p. 394 – 398.

[7]. Titov Yu.A., Slobodyanik N. S., Polubinskii V. V. Mechanisms for the formation of laminar titanates AIIn-4La4Tin-1O3n from coprecipitated component systems // Theoretical and Experimental Chemistry, 2012, V. 48, N 3, p. 189 – 193.

[8]. Nedilko S., Nedielko I., Scherbatskii V., Titov Yu., Virko S., Boyko V., Sheludko V. Luminescent properties of Eu3+ doped layered perovskite-like polycrystalline powders of the  BaLa2-xEuxTi3O10 (x = 0 – 2) titanate compounds // Functional Materials, 2012, V. 19, N 2, p. 197 – 201.

[9]. Polubinskii V.V., Titov Y.A., Belyavina N.M., Markiv V.Ya., Slobodyanik M.S., Chumak V.V., Nakonechna O.I. Synthesis and crystal structure of the A6B5O18 perovskite-like compounds // Solid State Sciences, 2014, March, V. 29, p. 1 – 5.

[10]. Chukova O., Gomenyuk O., Nedilko S., Polubinskii V., Scherbatsky V., Sheludko V. Titov Y. Luminescence processes in Me3LaNb3O12 (M = Ba, Sr) layered perovskites // Optical Materials, 2014, V. 36, N 10, p. 1709-1714.

[11]. Titov Yu., Nedilko S., Chornii V., Scherbatskii V., Belyavina N., Markiv V., Polubinskii V. Crystal structure and luminescence of layered perovskites Sr3LnBIIISnO8 (BIII = Sc, In) // Solid State Phenomena, 2015, V. 230,  p. 67 - 72.

[12]. Titov Y., Belyavina N., Slobodyanik M., Polubinskii V., Nakonechna O. Crystal structure of the Sr6Nb4ZrO18 slab perovskite-like compound // French Ukrainian Journal of Chemistry, 2015, V.3, N 2, p. 35-40.

[13]. Тітов Ю.О., Слободяник М.С., Кузьмін Р.М., Краєвська Я.А., Чумак В.В. Діелектричні та електропровідні властивості сполук типу AIILnnBIIInO3n+1 (AII = Sr, Ba, Ln = La, Eu, BIII = Sc, In, n = 1, 2) з шаруватою структурою  // Доповіді НАН України, 2017, № 1, с. 74 – 81.

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